Vegetal Polyphenol Extracts as Antioxidants for the Stabilization of PLA: Toward Fully Biobased Polymer Formulation

The use of natural antioxidants as substitutes for traditional synthetic stabilizers has been investigated for the stabilization of biobased and biodegradable polymers, with the aim of designing fully biobased plastic formulations. This study focused on the thermo- and photostabilization of poly­(lactic acid) (PLA) using vegetal polyphenol extracts as biosourced antioxidants. The polyphenols were extracted by microwave-assisted extraction from the valorization of vegetal waste, and their potential as antioxidant additives was evaluated (e.g., polyphenol content, composition, and antioxidant activity). PLA was then formulated with 2 wt % of the extracts exhibiting the highest antioxidant activities: green tea residues, pomegranate peels, grape marc, bramble leaves, and yellow onion peel extracts. The efficiency of the natural additives as thermal stabilizers was evaluated and compared with a synthetic antioxidant using rheological and thermal analyses. The results demonstrated the capacity of grape marc extract and pomegranate peel extract to significantly improve PLA thermal stability during processing and thermo-oxidation. Finally, photorheology was conducted to evaluate the influence of the bioadditives on the biopolyester photodegradation. The different polyphenol extracts seemed to significantly hinder the photo-oxidation of PLA and constitute very promising natural UV stabilizers, combining UV absorbers and antioxidant functions.