Geometric Optimisation of Quantum Thermodynamic Processes

Differential geometry offers a powerful framework for optimising and characterising finite-time thermodynamic processes, both classical and quantum. Here, we start by a pedagogical introduction to the notion of thermodynamic length. We review and connect different frameworks where it emerges in the...

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Veröffentlicht in:Entropy (Basel, Switzerland) Switzerland), 2020-09, Vol.22 (10), p.1076
Hauptverfasser: Abiuso, Paolo, Miller, Harry J D, Perarnau-Llobet, Martí, Scandi, Matteo
Format: Artikel
Sprache:eng
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Zusammenfassung:Differential geometry offers a powerful framework for optimising and characterising finite-time thermodynamic processes, both classical and quantum. Here, we start by a pedagogical introduction to the notion of thermodynamic length. We review and connect different frameworks where it emerges in the quantum regime: adiabatically driven closed systems, time-dependent Lindblad master equations, and discrete processes. A geometric lower bound on entropy production in finite-time is then presented, which represents a quantum generalisation of the original classical bound. Following this, we review and develop some general principles for the optimisation of thermodynamic processes in the linear-response regime. These include constant speed of control variation according to the thermodynamic metric, absence of quantum coherence, and optimality of small cycles around the point of maximal ratio between heat capacity and relaxation time for Carnot engines.
ISSN:1099-4300
1099-4300
DOI:10.3390/e22101076