Bis(2,2'-diamino-4,4'-bi-1,3-thia-zole-κN,N)bis-(nitrato-κO)lead(II) dihydrate

In the title compound, [Pb(NO(3))(2)(C(6)H(6)N(4)S(2))(2)]·2H(2)O, the Pb(II) cation is N,N'-chelated by two 2,2'-diamino-4,4'-bi-1,3-thia-zole (DABT) ligands and further is cis coordinated by two nitrate anions in a distorted PbN(4)O(2) octa-hedral geometry. One of the uncoordinated...

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Veröffentlicht in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2009-07, Vol.65 (Pt 8), p.m1002-m1003
Hauptverfasser: Liu, Bing-Xin, Xu, Duan-Jun
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Sprache:eng
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Zusammenfassung:In the title compound, [Pb(NO(3))(2)(C(6)H(6)N(4)S(2))(2)]·2H(2)O, the Pb(II) cation is N,N'-chelated by two 2,2'-diamino-4,4'-bi-1,3-thia-zole (DABT) ligands and further is cis coordinated by two nitrate anions in a distorted PbN(4)O(2) octa-hedral geometry. One of the uncoordinated water mol-ecules is close to an inversion center and is disordered equally over two sites. Intra-molecular N-H⋯N and N-H⋯O inter-actions are present. An extensive hydrogen-bonding network of types N-H⋯O, O-H⋯O, O-H⋯N and O-H⋯S consolidates the crystal structure.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536809029638