Bis(2,2'-diamino-4,4'-bi-1,3-thia-zole-κN,N)bis-(nitrato-κO)lead(II) dihydrate
In the title compound, [Pb(NO(3))(2)(C(6)H(6)N(4)S(2))(2)]·2H(2)O, the Pb(II) cation is N,N'-chelated by two 2,2'-diamino-4,4'-bi-1,3-thia-zole (DABT) ligands and further is cis coordinated by two nitrate anions in a distorted PbN(4)O(2) octa-hedral geometry. One of the uncoordinated...
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Veröffentlicht in: | Acta crystallographica. Section E, Structure reports online Structure reports online, 2009-07, Vol.65 (Pt 8), p.m1002-m1003 |
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Sprache: | eng |
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Zusammenfassung: | In the title compound, [Pb(NO(3))(2)(C(6)H(6)N(4)S(2))(2)]·2H(2)O, the Pb(II) cation is N,N'-chelated by two 2,2'-diamino-4,4'-bi-1,3-thia-zole (DABT) ligands and further is cis coordinated by two nitrate anions in a distorted PbN(4)O(2) octa-hedral geometry. One of the uncoordinated water mol-ecules is close to an inversion center and is disordered equally over two sites. Intra-molecular N-H⋯N and N-H⋯O inter-actions are present. An extensive hydrogen-bonding network of types N-H⋯O, O-H⋯O, O-H⋯N and O-H⋯S consolidates the crystal structure. |
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ISSN: | 1600-5368 1600-5368 |
DOI: | 10.1107/S1600536809029638 |