Non-toxic near-infrared light-emitting diodes

Harnessing cost-efficient printable semiconductor materials as near-infrared (NIR) emitters in light-emitting diodes (LEDs) is extremely attractive for sensing and diagnostics, telecommunications, and biomedical sciences. However, the most efficient NIR LEDs suitable for printable electronics rely on emissive materials containing precious transition metal ions (such as platinum), which have triggered concerns about their poor biocompatibility and sustainability. Here, we review and highlight the latest progress in NIR LEDs based on non-toxic and low-cost functional materials suitable for solution-processing deposition. Different approaches to achieve NIR emission from organic and hybrid materials are discussed, with particular focus on fluorescent and exciplex-forming host-guest systems, thermally activated delayed fluorescent molecules, aggregation-induced emission fluorophores, as well as lead-free perovskites. Alternative strategies leveraging photonic microcavity effects and surface plasmon resonances to enhance the emission of such materials in the NIR are also presented. Finally, an outlook for critical challenges and opportunities of non-toxic NIR LEDs is provided. [Display omitted] •Telecommunications and biomedical sensors will hugely benefit from the development of non-toxic NIR LEDs.•Both organic and hybrid materials reported remarkable performance in the 700- to 1000-nm range.•Aggregation and the energy gap law represent the toughest hurdles to overcome for efficient NIR emission in organic materials.•Leveraging AIE, TADF, and hybrid materials have proven successful in improving efficiencies.