Water and Aqueous Mixtures as Convenient Alternative Media for Organoselenium Chemistry

Even if water is the natural environment for bioorganic reactions, its use in organic chemistry is often severely limited by the high insolubility of the organic derivatives. In this review, we introduce some examples of the use of water to perform organoselenium chemistry. We mainly discuss the adv...

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Veröffentlicht in:	Molecules (Basel, Switzerland) Switzerland), 2016-11, Vol.21 (11), p.1482
Hauptverfasser:	Santi, Claudio, Jacob, Raquel G, Monti, Bonifacio, Bagnoli, Luana, Sancineto, Luca, Lenardão, Eder J
Format:	Artikel
Sprache:	eng
Schlagworte:	Catalysis Chemistry, Organic - methods coupling epoxide michael addition on-water reactions Organoselenium Compounds - chemistry oxidation Review selenium water Water - chemistry zinc
Online-Zugang:	Volltext
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Beschreibung
Zusammenfassung:	Even if water is the natural environment for bioorganic reactions, its use in organic chemistry is often severely limited by the high insolubility of the organic derivatives. In this review, we introduce some examples of the use of water to perform organoselenium chemistry. We mainly discuss the advantages of this medium when the recyclability is demonstrated and when the water can control the selectivity of a reaction or enhance the reaction rate.
ISSN:	1420-3049 1420-3049
DOI:	10.3390/molecules21111482