Fe-Sensitized Zeolite Supported TiO2 for the Degradation of Tetracycline Using Blue LED Irradiation

In this study, we investigated the photocatalytic degradation as a potential treatment of tetracycline (TC) antibiotic contaminated water using TiO 2 semiconductor. To expand the activity of TiO 2 into the visible light region and to enhance its adsorption capacity for TC, we explored its modification via sensitization with Fe ions and via immobilization on beta (BEA) zeolite support. The nano-sized beta zeolite, synthesized using the seed-assisted procedure, was used to immobilize TiO 2 initially prepared by the sol-gel method. The immobilized TiO 2 /BEA catalyst was further ion exchanged with Fe 3+ ions using FeCl 3 precursor. Fe 3+ modified TiO 2 /BEA (Fe-TiO 2 /BEA) catalyst was characterized using SEM, XRD, BET, UV-VIS DRS, and FTIR. After the immobilization of TiO 2 over BEA, the surface area of TiO 2 increased from 90 to 530 m 2 /g and similarly its TC adsorption efficiency increased from 10% to 33%. The photocatalytic performance of the Fe-TiO 2 /BEA was evaluated under blue LED light for TC degradation. Fe-TiO 2 /BEA exhibited higher TC removal efficiency (100%) compared to TiO 2 (80%) after 90 min of irradiation using 50 W blue LED light for a 250 mg/L initial catalyst concentration and 20 mg/L TC concentration. The enhanced performance of the final catalyst was a result of the expanded surface area due to the immobilization of the TiO 2 on the BEA zeolite, which resulted in an improved TC adsorption. Moreover, the presence of Fe 3+ ions reduced the band gap energy of the TiO 2, hence led to a red shift in its absorption spectrum to the visible light region and minimized the extent of the recombination of the charge carriers.