Features of the welded seam material crystalliza-tion in Ti-TiB alloy under electron-beam welding conditions

Natural metal composite materials represent a promising class of modern structural materials that need to be welded. Such materials can be welded by fusion, as has been established with the Ti-TiB alloy as an example. The enhanced operational properties of such materials are determined by the microstructure, which is characterized by the presence of microfibers of borides, carbides, or silicides in the metal matrix. To preserve the mechanical properties of materials in a welded joint, it is necessary to ensure the formation of reinforcing microfibers in the welded seam material. Determination of formation mechanism of boride microfibers, originated in the welded seam material, will become the basis for optimizing of fusion welding modes, in particular, electron beam welding mode. The purpose of this study is the determination of formation mechanism of boride microfibers originated in the welded seam material. Two most probable variants of the formation mechanism are analyzed, which involve eutectic decomposition during crystallization from a liquid melt or eutectoid decomposition from a metastable crystallized alloy. The third version is a mixed variant of the two above-mentioned mechanisms. In the article the results of metallographic analysis of features of boride phase distribution and an analysis of elemental composition of boride fibers based on local Auger electron spectroscopy are presented. The object of study was a Ti-TiB alloy joint obtained by electron-beam welding. The analysis factors were the features of size, orientation, and nature of the distribution of boride phase microfibers in different areas of the welded seam. The characteristic elemental composition of boride microfibers, which characterizes the correspondence to equilibrium phases, is also studied. The degree of deviation of the ratio of boron and titanium in such a phase from the thermodynamically equilibrium in different layers of the material of the welded seam, formed by an electron beam in vacuum, is determined. The dependence of boride phase distribution under various conditions of heat exchange in the welded seam material on the side surfaces and in the central regions is established. It is shown that some of boride microfibers formed in the material of the welded seam are characterized by a deviation from the thermodynamically stable composition ТіВn (n = 1) to ТіВn (n = 0.85). The dendritic nature of boride microfibers distribution and the presence of meta-stable phase for