A squarate-pillared titanium oxide quantum sieve towards practical hydrogen isotope separation

Separating deuterium from hydrogen isotope mixtures is of vital importance to develop nuclear energy industry, as well as other isotope-related advanced technologies. As one of the most promising alternatives to conventional techniques for deuterium purification, kinetic quantum sieving using porous...

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Veröffentlicht in:Nature communications 2023-07, Vol.14 (1), p.4189-4189, Article 4189
Hauptverfasser: Yan, Qingqing, Wang, Jing, Zhang, Linda, Liu, Jiaqi, Wahiduzzaman, Mohammad, Yan, Nana, Yu, Liang, Dupuis, Romain, Wang, Hao, Maurin, Guillaume, Hirscher, Michael, Guo, Peng, Wang, Sujing, Du, Jiangfeng
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Sprache:eng
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Zusammenfassung:Separating deuterium from hydrogen isotope mixtures is of vital importance to develop nuclear energy industry, as well as other isotope-related advanced technologies. As one of the most promising alternatives to conventional techniques for deuterium purification, kinetic quantum sieving using porous materials has shown a great potential to address this challenging objective. From the knowledge gained in this field; it becomes clear that a quantum sieve encompassing a wide range of practical features in addition to its separation performance is highly demanded to approach the industrial level. Here, the rational design of an ultra-microporous squarate pillared titanium oxide hybrid framework has been achieved, of which we report the comprehensive assessment towards practical deuterium separation. The material not only displays a good performance combining high selectivity and volumetric uptake, reversible adsorption-desorption cycles, and facile regeneration in adsorptive sieving of deuterium, but also features a cost-effective green scalable synthesis using chemical feedstock, and a good stability (thermal, chemical, mechanical and radiolytic) under various working conditions. Our findings provide an overall assessment of the material for hydrogen isotope purification and the results represent a step forward towards next generation practical materials for quantum sieving of important gas isotopes. Hydrogen isotope separation is key for developing technologies. Here authors present a squarate-pillared titanium oxide quantum sieve for deuterium separation, displaying impressive separation performance, cost-effective green scalable synthesis, and stability.
ISSN:2041-1723
2041-1723
DOI:10.1038/s41467-023-39871-x