Physical Origin of Diminishing Photocatalytic Efficiency for Recycled TiO2 Nanotubes and Ag-Loaded TiO2 Nanotubes in Organic Aqueous Solution

Arrays of titania nanotubes (TiO2NTs) were developed by electrochemical anodization and doped with silver on their surface by photodeposition to achieve TiO2NTs/Ag. It is found that only anatase TiO2NTs were formed, with the preferential growth direction perpendicular to the titanium substrate, and...

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Veröffentlicht in:Catalysts 2020-07, Vol.10 (7), p.737
Hauptverfasser: Wint, Theint Hay Mar, Smith, Michael F., Chanlek, Narong, Chen, Fuming, Oo, Than Zaw, Songsiriritthigul, Prayoon
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Sprache:eng
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Zusammenfassung:Arrays of titania nanotubes (TiO2NTs) were developed by electrochemical anodization and doped with silver on their surface by photodeposition to achieve TiO2NTs/Ag. It is found that only anatase TiO2NTs were formed, with the preferential growth direction perpendicular to the titanium substrate, and with the length and diameter of ~2 µm and 90–120 nm, respectively. The presence of Ag on the surface of TiO2NTs was also confirmed. The TiO2NTs and TiO2NTs/Ag were used as photocatalysts to decolorize the methylene blue (MB) aqueous solution. The photodegradation efficiency (PDE) is as high as 83% for TiO2NTs and 98% for TiO2NTs/Ag photocatalysts. This work focused on the investigation of the stability and recyclability of these photocatalysts in terms of efficiency and its physical origin by surface analysis using X-ray photoelectron spectroscopy (XPS). It is found that PDE diminishes from 83% to 76% in TiO2NTs upon eight recycling runs and from 98% to 80% in TiO2NTs/Ag upon six recycling runs. The XPS analysis revealed that the physical origin of diminishing efficiency is the carbon contamination on the surface of recycled TiO2NTs and a combination of carbon contamination and Ag leaching in recycled TiO2NTs/Ag.
ISSN:2073-4344
2073-4344
DOI:10.3390/catal10070737