(E)-1-Ferrocenyl-3-(2-meth-oxy-phen-yl)prop-2-en-1-one

The structure of the title compound, [Fe(C5H5)(C15H13O2)], consists of a ferrocenyl moiety and a 2-meth-oxy-phenyl group linked through a prop-2-en-1-one spacer in an E conformation. In the ferrocene unit, the substituted cyclo-penta-dienyl (Cps) ring and the unsubstituted cyclo-penta-dienyl ring (C...

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Veröffentlicht in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2014-03, Vol.70 (Pt 3), p.m108-m109
Hauptverfasser: Otaño Vega, Myrna R, Rivero, Kennett I, Montes González, Ingrid
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Sprache:eng
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Zusammenfassung:The structure of the title compound, [Fe(C5H5)(C15H13O2)], consists of a ferrocenyl moiety and a 2-meth-oxy-phenyl group linked through a prop-2-en-1-one spacer in an E conformation. In the ferrocene unit, the substituted cyclo-penta-dienyl (Cps) ring and the unsubstituted cyclo-penta-dienyl ring (Cp) are almost parallel to one another [dihedral angle = 1.78 (14)°], and the Cp and Cps rings are in a gauche conformation. The benzene ring is twisted by 10.02 (14) and 11.38 (11)° with respect to the Cp and Cps rings, respectively. In the crystal, mol-ecules are linked by weak C-H⋯O hydrogen bonds into supra-molecular chains running along the b-axis direction.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536814003912