Ultra‐robust stretchable electrode for e‐skin: In situ assembly using a nanofiber scaffold and liquid metal to mimic water‐to‐net interaction

The development of stretchable electronics could enhance novel interface structures to solve the stretchability–conductivity dilemma, which remains a major challenge. Herein, we report a nano‐liquid metal (LM)‐based highly robust stretchable electrode (NHSE) with a self‐adaptable interface that mimics water‐to‐net interaction. Based on the in situ assembly of electrospun elastic nanofiber scaffolds and electrosprayed LM nanoparticles, the NHSE exhibits an extremely low sheet resistance of 52 mΩ sq−1. It is not only insensitive to a large degree of mechanical stretching (i.e., 350% electrical resistance change upon 570% elongation) but also immune to cyclic deformation (i.e., 5% electrical resistance increases after 330 000 stretching cycles with 100% elongation). These key properties are far superior to those of the state‐of‐the‐art reports. Its robustness and stability are verified under diverse circumstances, including long‐term exposure to air (420 days), cyclic submersion (30 000 times), and resilience against mechanical damages. The combination of conductivity, stretchability, and durability makes the NHSE a promising conductor/electrode solution for flexible/stretchable electronics for applications such as wearable on‐body physiological signal detection, human–machine interaction, and heating e‐skin. The development of stretchable electronics could enhance novel interface structures to achieve electrical stability upon stretching and cyclic durability simultaneously, which remains a major challenge. Herein, authors (DOI: 10.1002/inf2.12302) reported a nano‐LM‐based highly robust stretchable electrode (NHSE) based on the in situ assembly of electrospun elastic nanofiber scaffolds and electrosprayed LM nanoparticles by mimicking the water‐to‐net interface. Without alloying or adding binder materials, the as‐prepared NHSE realises a self‐adaptable interface to achieve a super‐low resistance under high elongation and an exceptional electrical robustness upon cyclic external stimuli. The combination of conductivity, stretchability, and durability makes the NHSE a promising conductor/electrode solution for flexible/stretchable electronics for applications such as wearable on‐body physiological signal detection, human‐machine interaction, and heating e‐skin. [Correction added on 14 March 2022, after first online publication: Graphical image caption has been updated.]