Dibromido(dimethyl sulfoxide-κ O )(6-methyl-2,2′-bipyridine-κ 2 N , N ′)cadmium
In the title compound, [CdBr 2 (C 11 H 10 N 2 )(C 2 H 6 OS)], the Cd II atom is five-coordinated in a distorted trigonal–bipyramidal geometry by two N atoms from a 6-methyl-2,2′-bipyridine ligand, one O atom from a dimethyl sulfoxide ligand and two Br atoms. An intramolecular C—H...O hydrogen bond o...
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Veröffentlicht in: | Acta crystallographica. Section E, Structure reports online Structure reports online, 2012-08, Vol.68 (8), p.m1124-m1124 |
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Hauptverfasser: | , |
Format: | Artikel |
Sprache: | eng |
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Online-Zugang: | Volltext |
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Zusammenfassung: | In the title compound, [CdBr
2
(C
11
H
10
N
2
)(C
2
H
6
OS)], the Cd
II
atom is five-coordinated in a distorted trigonal–bipyramidal geometry by two N atoms from a 6-methyl-2,2′-bipyridine ligand, one O atom from a dimethyl sulfoxide ligand and two Br atoms. An intramolecular C—H...O hydrogen bond occurs. The crystal structure is stabilized by C—H...Br hydrogen bonds and π–π contacts between the pyridine rings [centroid–centroid distances = 3.582 (5) and 3.582 (5) Å]. |
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ISSN: | 1600-5368 1600-5368 |
DOI: | 10.1107/S1600536812033168 |