Bis{N-benzyl-N-[2-(thio-phen-2-yl)eth-yl]di-thio-carbamato-κ(2) S,S'}lead(II)

Bis{N-benzyl-N-[2-(thio-phen-2-yl)eth-yl]di-thio-carbamato-κ(2) S,S'}lead(II)

The mol-ecule of the title compound, [Pb(C14H14NS3)2], is located on a twofold rotation axis. The di-thio-carbamate anion S,S'-chelates to the Pb(II) atom, which shows a Ψ-trigonal-bipyramidal coordination. The thio-phene ring is disordered over two positions, the major component having 71.3 (7...

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Veröffentlicht in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2013-08, Vol.69 (Pt 8), p.m457-m457
Hauptverfasser: Sathiyaraj, E, Thirumaran, S, Sridhar, B, Selvanayagam, S
Format: Artikel
Sprache:eng
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Metal-Organic Papers
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Zusammenfassung:The mol-ecule of the title compound, [Pb(C14H14NS3)2], is located on a twofold rotation axis. The di-thio-carbamate anion S,S'-chelates to the Pb(II) atom, which shows a Ψ-trigonal-bipyramidal coordination. The thio-phene ring is disordered over two positions, the major component having 71.3 (7)% occupancy. The mol-ecular conformation is stabilized by intra-molecular C-H⋯S inter-actions.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536813019259