Radical Smiles Rearrangement: An Update

Radical Smiles Rearrangement: An Update

Over the decades the Smiles rearrangement and its variants have become essential synthetic tools in modern synthetic organic chemistry. In this mini-review we summarized some very recent results of the radical version of these rearrangements. The selected examples illustrate the synthetic power of t...

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Veröffentlicht in:Molecules (Basel, Switzerland) Switzerland), 2016-07, Vol.21 (7), p.878
Hauptverfasser: Allart-Simon, Ingrid, Gérard, Stéphane, Sapi, Janos
Format: Artikel
Sprache:eng
Schlagworte:
Chemical Sciences
Chemistry Techniques, Synthetic
Chemistry, Organic - methods
domino reactions
heterocycle
Organic chemistry
radical cascade
radical chemistry
Review
Smiles rearrangement
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Beschreibung
Zusammenfassung:Over the decades the Smiles rearrangement and its variants have become essential synthetic tools in modern synthetic organic chemistry. In this mini-review we summarized some very recent results of the radical version of these rearrangements. The selected examples illustrate the synthetic power of this approach, especially if it is incorporated into a domino process, for the preparation of polyfunctionalized complex molecules.
ISSN:1420-3049
1420-3049
DOI:10.3390/molecules21070878