Highly Impact-Resistant Block Polymer-Based Thermoplastic Elastomers with an Ionically Functionalized Rubber Phase

There has been a great deal of interest in incorporating noncovalent bonding groups into elastomers to achieve high strength. However, the impact resistance of such elastomers has not been evaluated, even though it is a crucial mechanical property in practical usage, partly because a large-scale synthetic scheme has not been established. By ionizing the rubber component in polystyrene-b-polyisoprene-b-polystyrene (SIS), we prepared several tens of grams of SIS-based elastomers with an ionically functionalized rubber phase and a sodium cation (i-SIS­(Na)) or a bulky barium cation (i-SIS­(Ba)). The i-SIS­(Na) and i-SIS­(Ba) exhibited very high tensile toughness of 520 and 280 MJ m–3, respectively. They also exhibited excellent compressive resistance. Moreover, i-SIS­(Ba) was demonstrated to have a higher impact resistance, that is, more protective of a material being covered compared to covering by typical high-strength glass fiber-reinforced plastic. As such elastomers can be produced at an industrial scale, they have great market potential as next-generation elastomeric materials.