Crystal structure of tris-(piperidinium) hydrogen sulfate sulfate

Crystal structure of tris-(piperidinium) hydrogen sulfate sulfate

In the title molecular salt, 3C5H12N(+)·HSO4 (-)·SO4 (2-), each cation adopts a chair conformation. In the crystal, the hydrogen sulfate ion is connected to the sulfate ion by a strong O-H⋯O hydrogen bond. The packing also features a number of N-H⋯O hydrogen bonds, which lead to a three-dimensional...

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Veröffentlicht in:Acta crystallographica. Section E, Crystallographic communications Crystallographic communications, 2015-12, Vol.71 (Pt 12), p.1444-1446
Hauptverfasser: Lukianova, Tamara J, Kinzhybalo, Vasyl, Pietraszko, Adam
Format: Artikel
Sprache:eng
Schlagworte:
crystal structure
hydrogen-bonding
organic–inorganic hybrid
piperidinium salts
Research Communications
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Zusammenfassung:In the title molecular salt, 3C5H12N(+)·HSO4 (-)·SO4 (2-), each cation adopts a chair conformation. In the crystal, the hydrogen sulfate ion is connected to the sulfate ion by a strong O-H⋯O hydrogen bond. The packing also features a number of N-H⋯O hydrogen bonds, which lead to a three-dimensional network structure. The hydrogen sulfate anion accepts four hydrogen bonds from two cations, whereas the sulfate ion, as an acceptor, binds to five separate piperidinium cations, forming seven hydrogen bonds.
ISSN:2056-9890
2056-9890
DOI:10.1107/S2056989015020538