Bis(μ-cobaltoceniumselenolate-1:2κ 2 Se : Se )bis[bis(cobaltoceniumselenolate-κ Se )mercury(II)] tetrakis(hexafluoridophosphate) acetonitrile disolvate
The title compound, [Co 6 Hg 2 (C 5 H 5 ) 6 (C 5 H 4 Se) 6 ](PF 6 ) 4 ·2CH 3 CN or [Hg 2 (CcSe) 6 ][PF 6 ] 4 ·2CH 3 CN (Cc = C 10 H 9 Co), was obtained as bright-orange needle-shaped crystals. It is a salt containing a tetracationic dimercury species with six cobaltoceniumselenolate ligands, four he...
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| Veröffentlicht in: | IUCrData 2021-10, Vol.6 (10), p.x211083, Article x211083 |
|---|---|
| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | The title compound, [Co
6
Hg
2
(C
5
H
5
)
6
(C
5
H
4
Se)
6
](PF
6
)
4
·2CH
3
CN or [Hg
2
(CcSe)
6
][PF
6
]
4
·2CH
3
CN (Cc = C
10
H
9
Co), was obtained as bright-orange needle-shaped crystals. It is a salt containing a tetracationic dimercury species with six cobaltoceniumselenolate ligands, four hexafluoridophosphate counter-ions and two acetonitrile solvent molecules. The cation (point group \overline{1}) has a bitetrahedral {Hg
2
Se
6
} core with two bridging Se atoms and four terminal Se atoms. |
|---|---|
| ISSN: | 2414-3146 2414-3146 |
| DOI: | 10.1107/S241431462101083X |