An Approach to Paracyclophane-Based Tetrathiafulvalenes: Synthesis and Characterization of a Pseudo-Geminal [2.2]Paracyclophane 1,3-Dithia-2-Thione

The synthesis of paracyclophane-based tetrathiafulvalene precursors is described in the context of the importance of these compounds in the field of material chemistry. bis(1,3-dithia-2-thione) was synthesized via the corresponding 1,3-dithiol-2-ylium salt. The latter was obtained by a synthetic pro...

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Veröffentlicht in:Molecules (Basel, Switzerland) Switzerland), 2020-11, Vol.25 (22), p.5262
Hauptverfasser: Bahrin, Lucian G, Hopf, Henning, Jones, Peter G, Birsa, Mihail L, Sarbu, Laura G
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Sprache:eng
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Zusammenfassung:The synthesis of paracyclophane-based tetrathiafulvalene precursors is described in the context of the importance of these compounds in the field of material chemistry. bis(1,3-dithia-2-thione) was synthesized via the corresponding 1,3-dithiol-2-ylium salt. The latter was obtained by a synthetic procedure that involves 4,15-bis(acetyl)[2.2]paracyclophane, a new compound of interest for many researchers.
ISSN:1420-3049
1420-3049
DOI:10.3390/molecules25225262