Dicarbonyl(η 5 -cyclopentadienyl)bis(trimethylphosphine)molybdenum(II) trifluoromethanesulfonate

Dicarbonyl(η 5 -cyclopentadienyl)bis(trimethylphosphine)molybdenum(II) trifluoromethanesulfonate

In the title compound, [Mo(C5H5)(CO)2(C3H9P)2]CF3SO3, the cationic complex displays a classical four-legged piano-stool square-pyramidal geometry with a trans configuration of the basal ligands around the Mo atom. The cyclopentadienyl (Cp) ligand occupies the apical position of the piano-stool confi...

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Veröffentlicht in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2008-11, Vol.64 (11), p.m1401-m1401
Hauptverfasser: Jali, Samuel, Friedrich, Holger B., Bala, Muhammad D.
Format: Artikel
Sprache:eng
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Zusammenfassung:In the title compound, [Mo(C5H5)(CO)2(C3H9P)2]CF3SO3, the cationic complex displays a classical four-legged piano-stool square-pyramidal geometry with a trans configuration of the basal ligands around the Mo atom. The cyclopentadienyl (Cp) ligand occupies the apical position of the piano-stool configuration. The average Mo-P bond length of the two trans PMe3 ligands is 2.474 (5) Å and the Mo-Cp centroid distance is 2.003 (2) Å.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536808032662