Construction of truncated-octahedral LiMn2O4 for battery-like electrochemical lithium recovery from brine

The extraction of lithium from salt lakes or seawater has attracted worldwide attention because of the explosive growth of global demand for lithium products. The LiMn2O4-based electrochemical lithium recovery system is one of the strongest candidates for commercial application due to its high inserted capacity and low energy consumption. However, the surface orientation of LiMn2O4 that facilitates Li diffusion happens to be prone to manganese dissolution making it a great challenge to obtain high lithium inserted capacity and long life simultaneously. Herein, we address this problem by designing a truncated octahedral LiMn2O4 (Tr-oh LMO) in which the dominant (111) facets minimize Mn dissolution while a small portion of (100) facets facilitate the Li diffusion. Thus, this Tr-oh LMO-based electrochemical lithium recovery system shows excellent Li recovery performance with high inserted capacity (20.25 mg g−1 per cycle) in simulated brine. In addition, the dissolution rate of manganese per 30 cycles is only 0.44% and the capacity maintained 85% of the initial after 30 cycles. These promising findings accelerate the practical application of LiMn2O4 in electrochemical lithium recovery. A novel truncated-octahedral LiMn2O4 electrode was constructed, which solved the problem that LiMn2O4 electrode could not obtain high cycle stability and high adsorption performance simultaneously in the process of lithium extraction from salt-lake. [Display omitted] •Novel truncated-octahedral LiMn2O4 electrode was constructed via a simple and mild method.•The prepared Tr-oh LMO has high extraction capacity and selectivity.•Tr-oh LMO electrode exhibits high cycle stability in the process of electrochemical lithium extraction.•The mechanism of electrochemical lithium extraction with Tr-oh LMO electrode was proposed.