5-Benzoyl-2-(5-bromo-1H-indol-3-yl)-4-(4-nitrophenyl)-1H-pyrrole-3-carbonitrile dimethyl sulfoxide monosolvate
The title compound, C26H15BrN4O3·C2H6OS, contains five rings. The indole unit is essentially planar [maximum deviation = 0.0067 (1) Å for the N atom]. The central pyrrole ring makes dihedral angles of 44.1 (2) and 51.3 (2)° with the pendant indole ring system and the nitrobenzene ring, respectively....
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Veröffentlicht in: | IUCrData 2016-04, Vol.1 (4), p.x160597 |
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Hauptverfasser: | , , , |
Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | The title compound, C26H15BrN4O3·C2H6OS, contains five rings. The indole unit is essentially planar [maximum deviation = 0.0067 (1) Å for the N atom]. The central pyrrole ring makes dihedral angles of 44.1 (2) and 51.3 (2)° with the pendant indole ring system and the nitrobenzene ring, respectively. The benzene ring is inclined with the central pyrrole ring by 51.9 (3)°. In the crystal, N—H...O hydrogen-bonding interactions between aromatic-H-atom donors and sulfoxide-O-atom acceptors result in the formation of inversion dimers with an R42(16) ring motif. The molecules are further linked into chains running along the c axis by N—H...O, C—H...O and C—H...N hydrogen bonds. |
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ISSN: | 2414-3146 2414-3146 |
DOI: | 10.1107/S2414314616005976 |