Chiral Hypervalent, Pentacoordinated Phosphoranes

Chiral Hypervalent, Pentacoordinated Phosphoranes

This review presents synthetic procedures applied to the preparation of chiral (mainly optically active) pentacoordinated, hypervalent mono and bicyclic phosphoranes. The mechanisms of their stereoisomerization and their selected interconversions are also presented.

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Molecules (Basel, Switzerland) Switzerland), 2016-11, Vol.21 (11), p.1573
Hauptverfasser: Krasowska, Dorota, Chrzanowski, Jacek, Kiełbasiński, Piotr, Drabowicz, Józef
Format: Artikel
Sprache:eng
Schlagworte:
Anions - chemistry
Berry pseudorotation
Chemistry Techniques, Synthetic
chirality
Cycloaddition Reaction
Hydrolysis
hypervalency
phosphoranes
Phosphoranes - chemical synthesis
Phosphoranes - chemistry
Review
Stereoisomerism
turnstile rotation
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:This review presents synthetic procedures applied to the preparation of chiral (mainly optically active) pentacoordinated, hypervalent mono and bicyclic phosphoranes. The mechanisms of their stereoisomerization and their selected interconversions are also presented.
ISSN:1420-3049
1420-3049
DOI:10.3390/molecules21111573