( E )-2-[1-(3-Amino-4-chlorophenylimino)ethyl]-4-bromophenol
The title Schiff base compound, C14H12BrClN2O, exists in an E configuration with respect to the central C=N double bond. The amino group adopts a pyramidal configuration. The dihedral angle between the two benzene rings is 76.88 (10)° and an intramolecular O—H...N hydrog...
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Veröffentlicht in: | Acta crystallographica. Section E, Structure reports online Structure reports online, 2010-04, Vol.66 (4), p.o883-o883 |
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Hauptverfasser: | , , , , |
Format: | Artikel |
Sprache: | eng |
Online-Zugang: | Volltext |
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Zusammenfassung: | The title Schiff base compound, C14H12BrClN2O, exists in an E configuration with respect to the central C=N double bond. The amino group adopts a pyramidal configuration. The dihedral angle between the two benzene rings is 76.88 (10)° and an intramolecular O—H...N hydrogen bond forms a six-membered ring, generating an S(6) ring motif. In the crystal structure, molecules are linked into chains along [010] via N—H...O hydrogen bonds. The presence of π–π interactions [centroid–centroid distance = 3.6244 (12) Å] further stabilizes the crystal structure. |
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ISSN: | 1600-5368 1600-5368 |
DOI: | 10.1107/S1600536810009773 |