1,2-Diphenyl-2-(m-tolylamino)ethanoneDedicated to the memory of Professor Jos #233; Manuel Concell #243;n

The title compound, C21H19NO, belongs to the family of α-aminoketones. The structure contains three benzene rings, two of which [the phenyl ring in the 1-position (B) and the methylaniline ring (A)] are nearly coplanar [dihedral angle = 5.4 (1)°], whereas the phenyl ring...

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Veröffentlicht in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2010-05, Vol.66 (5), p.o1107-o1107
Hauptverfasser: Rafael Mendoza Mero&#241, o, Felix N&#225, poles Esculary, Laura Men&#233, ndez Taboada, Santiago Garc&#237, a-Granda
Format: Artikel
Sprache:eng
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Zusammenfassung:The title compound, C21H19NO, belongs to the family of α-aminoketones. The structure contains three benzene rings, two of which [the phenyl ring in the 1-position (B) and the methylaniline ring (A)] are nearly coplanar [dihedral angle = 5.4 (1)°], whereas the phenyl ring in the 2-position (C) is nearly normal to them [dihedral angles = 81.8 (1) and 87.0 (1)° for A/C and B/C, respectively]. The conformation of the N—H bond is syn to the C=O bond, favouring the formation of a centrosymmetric dimer of molecules in the crystal structure. The molecular packing is consolidated by this N—H...O hydrogen-bonding network.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536810013371