Persistent Photoluminescence and Mechanoluminescence of a Highly Sensitive Pressure and Temperature Gauge in Combination with a 3D‐Printable Optical Coding Platform

Distinct types of luminescence that are activated by various stimuli in a single material offer exciting developmental opportunities for functional materials. A versatile sensing platform that exhibits photoluminescence (PL), persistent luminescence (PersL), and mechanoluminescence (ML) is introduced, which enables the sensitive detection of temperature, pressure, and force/stress. The developed Sr2MgSi2O7:Eu2+/Dy3+ material exhibits a linear relationship between ML intensity and force and can be used as an ML stress sensor. Additionally, the bandwidth of the PL emission band and the PL lifetime of this material are remarkably sensitive to temperature, with values of ≈0.05 nm K−1 and 1.29%/K, respectively. This study demonstrates PersL pressure sensing for the first time, using long‐lasting (seconds) lifetime as a manometric parameter. The developed material functions as an exceptionally sensitive triple‐mode visual pressure sensor; specifically, it exhibits: i) a sensitivity of ≈−297.4 cm GPa−1 (8.11 nm GPa−1) in bandshift mode, ii) a sensitivity of ≈272.7 cm−1/GPa (14.8 nm GPa−1) in bandwidth mode, and iii) a sensitivity of 42%GPa−1 in PL‐lifetime mode, which is the highest value reported to date. Notably, anti‐counterfeiting, night‐vision safety‐sign, 8‐bit optical‐coding, and QR‐code applications that exhibit intense PersL are demonstrated by 3D‐printing the studied material in combination with a polymer. A multifunctional sensing platform of temperature, pressure, and stress is built, which is based on three different types of luminescence, photo‐, persistent‐, and mechano‐luminescence. Combined with the 3D‐printing technique, it also has practical uses like anti‐counterfeiting, night‐vision safety‐sign, and 8‐bit optical‐coding and QR codes.