1-Methyl-3,3-bis-[(4-methyl-phen-yl)sulfan-yl]piperidin-2-one

The piperidone ring in the title compound, C(20)H(23)NOS(2), has a half-chair distorted to a twisted-boat conformation [Q(T) = 0.5200 (17) Å]. One of the S-bound benzene rings is almost perpendicular to the least-squares plane through the piperidone ring, whereas the other is not [dihedral angles =...

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Veröffentlicht in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2011-10, Vol.67 (Pt 10), p.o2759-o2759
Hauptverfasser: Zukerman-Schpector, Julio, Olivato, Paulo R, Cerqueira, Jr, Carlos R, Santos, Jean M M, Ng, Seik Weng, Tiekink, Edward R T
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Sprache:eng
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Zusammenfassung:The piperidone ring in the title compound, C(20)H(23)NOS(2), has a half-chair distorted to a twisted-boat conformation [Q(T) = 0.5200 (17) Å]. One of the S-bound benzene rings is almost perpendicular to the least-squares plane through the piperidone ring, whereas the other is not [dihedral angles = 75.28 (5) and 46.41 (5) Å, respectively]. In the crystal, the presence of C-H⋯O and C-H⋯π inter-actions leads to the formation of supra-molecular layers in the ab plane.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536811037111