Graphene’s nonlinear-optical physics revealed through exponentially growing self-phase modulation

Graphene is considered a record-performance nonlinear-optical material on the basis of numerous experiments. The observed strong nonlinear response ascribed to the refractive part of graphene’s electronic third-order susceptibility χ (3) cannot, however, be explained using the relatively modest χ (3) value theoretically predicted for the 2D material. Here we solve this long-standing paradox and demonstrate that, rather than χ (3) -based refraction, a complex phenomenon which we call saturable photoexcited-carrier refraction is at the heart of nonlinear-optical interactions in graphene such as self-phase modulation. Saturable photoexcited-carrier refraction is found to enable self-phase modulation of picosecond optical pulses with exponential-like bandwidth growth along graphene-covered waveguides. Our theory allows explanation of these extraordinary experimental results both qualitatively and quantitatively. It also supports the graphene nonlinearities measured in previous self-phase modulation and self-(de)focusing ( Z -scan) experiments. This work signifies a paradigm shift in the understanding of 2D-material nonlinearities and finally enables their full exploitation in next-generation nonlinear-optical devices. Graphene enables extraordinary nonlinear-optical refraction, far exceeding predictions based on conventional nonlinear-susceptibility theory. Here, Vermeulen et al. show that rather than the nonlinear susceptibility, a complex saturable refraction process is central to graphene’s unusual behavior.