Confinement-induced demixing and crystallization

We simulate a strongly size-disperse hard-sphere fluid confined between two parallel hard walls. We find that confinement induces crystallization into n-layered hexagonal lattices and a novel honeycomb-shaped structure, facilitated by fractionation. The onset of freezing prevents the formation of a stable glass phase and occurs at much smaller packing fraction than in bulk. Varying the wall separation triggers solid-to-solid transitions and a systematic change in the size distribution of crystalline particles, which we rationalize using a semiquantitative theory. We show that the crystallization can be exploited in a wedge geometry to demix particles of different sizes.