[1-(3-Nitro-phen-yl)-2,3-dihydro-1H-naphtho[1,2-e][1,3]oxazin-3-ylidine]malonaldehyde
The oxazine ring in the title compound, C(21)H(14)N(2)O(5), adopts a flattened boat conformation. The nitro-phenyl ring and the naphthalene ring system enclose a dihedral angle of 89.2 (1)°. An intra-molecular hydrogen bond is formed between the NH group and one of the adjacent carbonyl O atoms. In...
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Veröffentlicht in: | Acta crystallographica. Section E, Structure reports online Structure reports online, 2009-02, Vol.65 (Pt 3), p.o582-o582 |
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Hauptverfasser: | , , , , |
Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | The oxazine ring in the title compound, C(21)H(14)N(2)O(5), adopts a flattened boat conformation. The nitro-phenyl ring and the naphthalene ring system enclose a dihedral angle of 89.2 (1)°. An intra-molecular hydrogen bond is formed between the NH group and one of the adjacent carbonyl O atoms. In addition, the NH group forms an inter-molecular hydrogen bond to a symmetry equivalent of this carbonyl O atom, connecting the mol-ecules into centrosymmetric dimers. The structure also contains C-H⋯O inter-molecular inter-actions. |
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ISSN: | 1600-5368 1600-5368 |
DOI: | 10.1107/S1600536809006023 |