[1-(3-Nitro-phen-yl)-2,3-dihydro-1H-naphtho[1,2-e][1,3]oxazin-3-ylidine]malonaldehyde

The oxazine ring in the title compound, C(21)H(14)N(2)O(5), adopts a flattened boat conformation. The nitro-phenyl ring and the naphthalene ring system enclose a dihedral angle of 89.2 (1)°. An intra-molecular hydrogen bond is formed between the NH group and one of the adjacent carbonyl O atoms. In...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2009-02, Vol.65 (Pt 3), p.o582-o582
Hauptverfasser: Nizammohideen, M, Subbiahpandi, A, Selvam, N Panneer, Perumal, P T, Damodiran, M
Format: Artikel
Sprache:eng
Schlagworte:
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:The oxazine ring in the title compound, C(21)H(14)N(2)O(5), adopts a flattened boat conformation. The nitro-phenyl ring and the naphthalene ring system enclose a dihedral angle of 89.2 (1)°. An intra-molecular hydrogen bond is formed between the NH group and one of the adjacent carbonyl O atoms. In addition, the NH group forms an inter-molecular hydrogen bond to a symmetry equivalent of this carbonyl O atom, connecting the mol-ecules into centrosymmetric dimers. The structure also contains C-H⋯O inter-molecular inter-actions.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536809006023