Bis(2-carboxyquinolinium) hexachloridostannate(IV) dihydrate

Bis(2-carboxyquinolinium) hexachloridostannate(IV) dihydrate

In the hydrated title salt, (C 10 H 8 NO 2 ) 2 [SnCl 6 ]·2H 2 O, the tin(IV) atom is located about a center of inversion. In the crystal structure, the organic cation, the octahedral inorganic anion and the water molecule of crystallization interact through O—H...O, N—H...O and O—H...Cl hydrogen bon...

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Veröffentlicht in:IUCrData 2024-08, Vol.9 (8), p.x240826, Article x240826
Hauptverfasser: Benhamada, Mohamed Siradj Eddine, Benlatreche, Tarek, Ghallab, Rochdi, Dénès, George, Merazig, Hocine
Format: Artikel
Sprache:eng
Schlagworte:
[sncl6]2– anion
crystal structure
hydrogen-bonding
π–π stacking
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Beschreibung
Zusammenfassung:In the hydrated title salt, (C 10 H 8 NO 2 ) 2 [SnCl 6 ]·2H 2 O, the tin(IV) atom is located about a center of inversion. In the crystal structure, the organic cation, the octahedral inorganic anion and the water molecule of crystallization interact through O—H...O, N—H...O and O—H...Cl hydrogen bonds, supplemented by weak π–π stacking between neighboring cations, and C—Cl...π interactions.
ISSN:2414-3146
2414-3146
DOI:10.1107/S2414314624008265