Crystal structure of 1-heptafluorotolyl- closo -1,2-dicarbadodecaborane

The molecular structure of the title compound 1-(2′,3′,5′,6′-tetrafluoro-4′-trifluoromethylphenyl)- closo -1,2-dicarbadodecaborane, C 9 H 11 B 10 F 7 , features an intramolecular ortho -F...H2 hydrogen bond [2.11 (2) Å], which is responsible for an orientation of the heptafluorotolyl substituent in...

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Veröffentlicht in:	Acta crystallographica. Section E, Crystallographic communications Crystallographic communications, 2019-04, Vol.75 (4), p.512-515
Hauptverfasser:	Watson, James D., Benton, Amanda, Tricas, Hugo, Rosair, Georgina M., Welch, Alan J.
Format:	Artikel
Sprache:	eng
Schlagworte:	carborane crystal structure intramolecular F...H hydrogen-bond
Online-Zugang:	Volltext
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Zusammenfassung:	The molecular structure of the title compound 1-(2′,3′,5′,6′-tetrafluoro-4′-trifluoromethylphenyl)- closo -1,2-dicarbadodecaborane, C 9 H 11 B 10 F 7 , features an intramolecular ortho -F...H2 hydrogen bond [2.11 (2) Å], which is responsible for an orientation of the heptafluorotolyl substituent in which the plane of the aryl ring nearly eclipses the C1—C2 cage connectivity.
ISSN:	2056-9890 2056-9890
DOI:	10.1107/S2056989019004067