The kinetics and mechanism of the sulfur dioxide oxidation by the oxygen in the presence of the cobalt and nickel complexes, fixed on polymer matrix

The kinetics and mechanism of the sulfur dioxide oxidation by the oxygen in the presence of the cobalt and nickel complexes, fixed on polymer matrix

Catalytic sulphur dioxide oxidation by oxygen on the cobalt and nickel complexes fixed on polyetheleneamine was investigated. On the base of kinetics study it was established that SO2 and oxygen interact in inner sphere mechanism. UV-spectra and quantum-chemical calculations are presented, and on th...

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Veröffentlicht in:Eurasian chemico-technological journal 2016-04, Vol.1 (1), p.65-81
Hauptverfasser: Emelyanova, V.S., Zhubanov, K.A., Shakieva, T.V., Yuldasheva, G.A.
Format: Artikel
Sprache:eng
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Zusammenfassung:Catalytic sulphur dioxide oxidation by oxygen on the cobalt and nickel complexes fixed on polyetheleneamine was investigated. On the base of kinetics study it was established that SO2 and oxygen interact in inner sphere mechanism. UV-spectra and quantum-chemical calculations are presented, and on the base of them the ways of oxygen activation are discussed.
ISSN:1562-3920
2522-4867
DOI:10.18321/ectj348