Crystal structure of ( E )-3-(2-hy-droxy-4-methyl-phen-yl)-1-(2,4,6-tri-meth-oxy-phen-yl)prop-2-en-1-one

The title chalcone derivative, C H O , adopts a configuration with respect to the olefinic C=C double bond. The 2-hy-droxy-4-methyl-phenyl ring is coplanar with the attached enone bridge [torsion angle = -179.96 (14)°], where this plane is nearly perpendicular to the 2,4,6-tri-meth-oxy-phenyl ring [...

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Veröffentlicht in:Acta crystallographica. Section E, Crystallographic communications Crystallographic communications, 2019-09, Vol.75 (Pt 9), p.1379-1382
Hauptverfasser: Jumaah, Maadh, Kwong, Huey Chong, Khairuddean, Melati
Format: Artikel
Sprache:eng
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Zusammenfassung:The title chalcone derivative, C H O , adopts a configuration with respect to the olefinic C=C double bond. The 2-hy-droxy-4-methyl-phenyl ring is coplanar with the attached enone bridge [torsion angle = -179.96 (14)°], where this plane is nearly perpendicular to the 2,4,6-tri-meth-oxy-phenyl ring [dihedral angle = 75.81 (8)°]. In the crystal, mol-ecules are linked into chains propagating along [010] by an O-H⋯O hydrogen bond. These chains are further connected into centrosymmetric dimer chains weak C-H⋯O inter-actions. The conformations of related chalcone derivatives are surveyed and all of these structures adopt a skeleton with two almost orthogonal aromatic rings.
ISSN:2056-9890
2056-9890
DOI:10.1107/S2056989019011289