Crystal structure and Hirshfeld surface analysis of (1 H -imidazole-κ N 3 )[ N -(2-oxidobenzylidene)tyrosinato-κ 3 O , N , O ′]copper(II)

Crystal structure and Hirshfeld surface analysis of (1 H -imidazole-κ N 3 )[ N -(2-oxidobenzylidene)tyrosinato-κ 3 O , N , O ′]copper(II)

The title copper(II) complex, [Cu(C 16 H 13 NO 4 )(C 3 H 4 N 2 )], consists of a tridentate ligand synthesized from L-tyrosine and salicylaldehyde. One imidazole molecule is additionally coordinating to the copper(II) ion. The crystal structure features N—H...O, O—H...O and C—H...O hydrogen bonds. T...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Acta crystallographica. Section E, Crystallographic communications Crystallographic communications, 2023-07, Vol.79 (7), p.596-599
Hauptverfasser: Suzuki, Soma, Akiyama, Yukihito, Nakane, Daisuke, Akitsu, Takashiro
Format: Artikel
Sprache:eng
Schlagworte:
amino acid
copper
crystal structure
hirshfeld analysis
Research Communications
schiff base complex
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:The title copper(II) complex, [Cu(C 16 H 13 NO 4 )(C 3 H 4 N 2 )], consists of a tridentate ligand synthesized from L-tyrosine and salicylaldehyde. One imidazole molecule is additionally coordinating to the copper(II) ion. The crystal structure features N—H...O, O—H...O and C—H...O hydrogen bonds. The Hirshfeld surface analysis indicates that the most important contributions to the packing are from H...H (37.9%), C...H (28.2%) and O...H/H...O (21.2%) contacts.
ISSN:2056-9890
2056-9890
DOI:10.1107/S2056989023004735