Boosting the Capacitive Performance of Supercapacitors by Hybridizing N, P-Codoped Carbon Polycrystalline with Mn3O4-Based Flexible Electrodes
Chitosan, a biomass raw material, was utilized as a carbon skeleton source and served as a nitrogen (N) atom dopant in this study. By co-doping phosphorus (P) atoms from H3PO4 and nitrogen (N) atoms with a carbon (C) skeleton and hybridizing them with Mn3O4 on a carbon fiber cloth (CC), an Mn3O4@NPC...
Gespeichert in:
Veröffentlicht in: | Nanomaterials (Basel, Switzerland) Switzerland), 2023-07, Vol.13 (14), p.2060 |
---|---|
Hauptverfasser: | , |
Format: | Artikel |
Sprache: | eng |
Schlagworte: | |
Online-Zugang: | Volltext |
Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
Zusammenfassung: | Chitosan, a biomass raw material, was utilized as a carbon skeleton source and served as a nitrogen (N) atom dopant in this study. By co-doping phosphorus (P) atoms from H3PO4 and nitrogen (N) atoms with a carbon (C) skeleton and hybridizing them with Mn3O4 on a carbon fiber cloth (CC), an Mn3O4@NPC/CC electrode was fabricated, which exhibited an excellent capacitive performance. The N, P-codoped carbon polycrystalline material was hybridized with Mn3O4 during the chitosan carbonization process. This carbon polycrystalline structure exhibited an enhanced conductivity and increased mesopore content, thereby optimizing the micropore/mesopore ratio in the electrode material. This optimization contributed to the improved storage, transmission, and diffusion of electrolyte ions within the Mn3O4@NPC electrode. The electrochemical behavior was evaluated via cyclic voltammetry and galvanostatic charge–discharge tests using a 1 M Na2SO4 electrolyte. The capacitance significantly increased to 256.8 F g−1 at 1 A g−1, and the capacitance retention rate reached 97.3% after 5000 charge/discharge cycles, owing to the higher concentration of the P-dopant in the Mn3O4@NPC/CC electrode. These findings highlight the tremendous potential of flexible supercapacitor electrodes in various applications. |
---|---|
ISSN: | 2079-4991 2079-4991 |
DOI: | 10.3390/nano13142060 |