Equilibrium and kinetics studies of naproxen adsorption onto novel magnetic graphene oxide functionalized with hybrid glycidoxy-amino propyl silane

•A hybrid silica-gel was decorated on graphene oxide to prepare adsorbent.•Silica-gel adsorbent used for the removal of naproxen from wastewater.•The experimental process was evaluated through isotherm models.•Langmuir adsorption capacity was obtained 196 mg g−1 for naproxen at pH 5. A hybrid silica...

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Veröffentlicht in:Environmental challenges (Amsterdam, Netherlands) Netherlands), 2021-08, Vol.4, p.100106, Article 100106
Hauptverfasser: Mohammadi Nodeh, Mohammad Kazem, Kanani, Narmin, Beirak Abadi, Elahe, Sereshti, Hassan, Barghi, Anahita, Rezania, Shahabaldin, Nabi bidhendi, Gholamreza
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Sprache:eng
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Zusammenfassung:•A hybrid silica-gel was decorated on graphene oxide to prepare adsorbent.•Silica-gel adsorbent used for the removal of naproxen from wastewater.•The experimental process was evaluated through isotherm models.•Langmuir adsorption capacity was obtained 196 mg g−1 for naproxen at pH 5. A hybrid silica-gel (3-glycidoxypropyl)trimethoxysilane/(3-aminopropyl)triethoxysilane magnetic graphene oxide (GPTMS/APTMS-MGO) nanocomposite was synthesized and used as an adsorbent for the magnetic removal of naproxen from water samples. The adsorbent was characterized using Fourier transform-infrared (FT-IR) spectroscopy, field emission-scanning electron microscopy (FE-SEM), energy-dispersive X-ray (EDX) spectroscopy, and transmission electron microscopy (TEM). The isotherm and kinetic studies showed that the data were fitted with Langmuir isotherm and pseudo-second-order kinetic models. The high adsorption capacity of 196 mg g−1 was obtained that indicated a monolayer sorption mechanism. The method was successfully applied for the removal of naproxen from wastewater samples and the removal efficiencies of 84–95% were obtained.
ISSN:2667-0100
2667-0100
DOI:10.1016/j.envc.2021.100106