Crystal structure of [3-(1H-benzimidazol-2-yl)propano-ato-κN (3)][3-(1H-benzimid-azol-2-yl)propanoic acid-κN (3)]copper(I)

In the title compound, [Cu(C10H9N2O2)(C10H10N2O2)], the Cu(I) ion is situated at a crystallographic centre of inversion and is coordinated in a linear environment by two benzimidazole N atoms from two symmetry-related 2-propanoic-1H-benzimidazole ligands. The ligands are disordered in a sense that s...

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Veröffentlicht in:Acta crystallographica. Section E, Crystallographic communications Crystallographic communications, 2015-01, Vol.71 (Pt 1), p.m5-m6
Hauptverfasser: Liu, Zhimin, Zheng, Shengrun, Feng, Sisi
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Sprache:eng
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Zusammenfassung:In the title compound, [Cu(C10H9N2O2)(C10H10N2O2)], the Cu(I) ion is situated at a crystallographic centre of inversion and is coordinated in a linear environment by two benzimidazole N atoms from two symmetry-related 2-propanoic-1H-benzimidazole ligands. The ligands are disordered in a sense that statistically one of the carb-oxy-lic acid groups in each mol-ecule is deprotonated. In the crystal, O-H⋯O hydrogen bonds link the mol-ecules into chains along the a-axis direction. These chains are additionally linked into infinite two-dimensional networks in the ab plane by N-H⋯O hydrogen bonds.
ISSN:2056-9890
2056-9890
DOI:10.1107/S2056989014026656