Diethyl 2-{[2-(trifluoromethyl)anilino]methylidene}propanedioate

The title compound, C15H16F3NO4, is an N-substituted derivative of ortho-trifluoromethylaniline featuring a twofold Michael system. The least-squares planes defined by the atoms of the phenyl ring and the atoms of the Michael system enclose an angle of 15.52 (5)°. Apart from class...

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Veröffentlicht in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2012-02, Vol.68 (2), p.o514-o515
Hauptverfasser: Garudachari, B., Isloor, Arun M., Satyanarayan, M. N., Gerber, Thomas, Hosten, Eric, Betz, Richard
Format: Artikel
Sprache:eng
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Zusammenfassung:The title compound, C15H16F3NO4, is an N-substituted derivative of ortho-trifluoromethylaniline featuring a twofold Michael system. The least-squares planes defined by the atoms of the phenyl ring and the atoms of the Michael system enclose an angle of 15.52 (5)°. Apart from classical intramolecular N—H...O and N—H...F hydrogen bonds, intermolecular C—H...O contacts are observed, the latter connecting the molecules into chains along [110]. The shortest intercentroid distance between two aromatic systems is 3.6875 (9) Å.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536812002590