Design and characterization of a new oxidation flow reactor for laboratory and long-term ambient studies

Oxidation flow reactors (OFRs) are frequently used to study the formation and evolution of secondary aerosol (SA) in the atmosphere and have become valuable tools for improving the accuracy of model simulations and for depicting and accelerating realistic atmospheric chemistry. Driven by rapid development of OFR techniques and the increasing appreciation of their wide application, we designed a new all-Teflon reactor, the Particle Formation Accelerator (PFA) OFR, and characterized it in the laboratory and with ambient air. A series of simulations and experiments were performed to characterize (1) flow profiles in the reactor using computational fluid dynamics (CFD) simulations, (2) the UV intensity distribution in the reactor and the influence of it and varying O.sub.3 concentration and relative humidity (RH) on the resulting equivalent OH exposure (OH.sub.exp ), (3) transmission efficiencies for gases and particles, (4) residence time distributions (RTDs) for gases and particles using both computational simulations and experimental verification, (5) the production yield of secondary organic aerosol (SOA) from oxidation of α-pinene and m-xylene, (6) the effect of seed particles on resulting SA concentration, and (7) SA production from ambient air in Riverside, CA, US. The reactor response and characteristics are compared with those of a smog chamber (Caltech) and of other oxidation flow reactors: the Toronto Photo-Oxidation Tube (TPOT), the Caltech Photooxidation Flow Tube (CPOT), the TUT Secondary Aerosol Reactor (TSAR), quartz and aluminum versions of Potential Aerosol Mass reactors (PAMs), and the Environment and Climate Change Canada OFR (ECCC-OFR).