The Henry reaction in [Bmim][PF₆]-based microemulsions promoted by acylase

The Henry reaction in [Bmim][PF₆]-based microemulsions promoted by acylase

An environmentally-friendly, enzyme-promoted procedure for the Henry reaction was first studied using water-in-[Bmim][PF6] microemulsions as reaction medium. The Amano acylase from Aspergillus oryzae showed better catalytic activity for the addition reactions of nitromethane with a series of aromati...

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Veröffentlicht in:Molecules (Basel, Switzerland) Switzerland), 2013-11, Vol.18 (11), p.13910-13919
Hauptverfasser: Xia, Wen-Jian, Xie, Zong-Bo, Jiang, Guo-Fang, Le, Zhang-Gao
Format: Artikel
Sprache:eng
Schlagworte:
acylase
Aldehydes - chemistry
Aldehydes - metabolism
Amidohydrolases - metabolism
Aspergillus oryzae - enzymology
enzyme promiscuity
Enzymes
Henry reaction
Microemulsions
Solvents
water-in-[Bmim][PF6] microemulsion
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Beschreibung
Zusammenfassung:An environmentally-friendly, enzyme-promoted procedure for the Henry reaction was first studied using water-in-[Bmim][PF6] microemulsions as reaction medium. The Amano acylase from Aspergillus oryzae showed better catalytic activity for the addition reactions of nitromethane with a series of aromatic aldehydes, and a highest yield of 90% was obtained.
ISSN:1420-3049
1420-3049
DOI:10.3390/molecules181113910