Pd@[nBu₄][Br] as a Simple Catalytic System for N-Alkylation Reactions with Alcohols

Palladium nanoparticles, simply and briefly generated in commercial and cheap onium salts using supercritical carbon dioxide, have been found to be an effective catalytic system for additive free N-alkylation reaction using alcohols via cascade oxidation/condensation/reduction steps.

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Bibliographische Detailangaben
Veröffentlicht in:	Molecules (Basel, Switzerland) Switzerland), 2016-08, Vol.21 (8), p.1042
Hauptverfasser:	Cacciuttolo, Bastien, Pascu, Oana, Aymonier, Cyril, Pucheault, Mathieu
Format:	Artikel
Sprache:	eng
Schlagworte:	Alcohol Alcohols - chemistry Alkylation Amines - chemistry Amino acids Carbon dioxide Carbon Dioxide - chemistry Catalysis Chemical Sciences Communication Hydrogen Material chemistry N-alkylation nanoparticle Nanoparticles Nanoparticles - chemistry Nanoparticles - ultrastructure Onium Compounds - chemistry onium salt Oxidation Oxidation-Reduction Palladium - chemistry
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Beschreibung
Zusammenfassung:	Palladium nanoparticles, simply and briefly generated in commercial and cheap onium salts using supercritical carbon dioxide, have been found to be an effective catalytic system for additive free N-alkylation reaction using alcohols via cascade oxidation/condensation/reduction steps.
ISSN:	1420-3049 1420-3049
DOI:	10.3390/molecules21081042