Interface strain in vertically stacked two-dimensional heterostructured carbon-MoS2 nanosheets controls electrochemical reactivity

Two-dimensional (2D) materials offer numerous advantages for electrochemical energy storage and conversion due to fast charge transfer kinetics, highly accessible surface area, and tunable electronic and optical properties. Stacking of 2D materials generates heterogeneous interfaces that can modify native chemical and physical material properties. Here, we demonstrate that local strain at a carbon-MoS 2 interface in a vertically stacked 2D material directs the pathway for chemical storage in MoS 2 on lithium metal insertion. With average measured MoS 2 strain of ∼0.1% due to lattice mismatch between the carbon and MoS 2 layers, lithium insertion is facilitated by an energy-efficient cation-exchange transformation. This is compared with low-voltage lithium intercalation for unstrained MoS 2 . This observation implies that mechanical properties of interfaces in heterogeneous 2D materials can be leveraged to direct energetics of chemical processes relevant to a wide range of applications such as electrochemical energy storage and conversion, catalysis and sensing. Two-dimensional materials are promising for electrochemical energy storage, conversion, catalysis, and sensing. Here the authors leverage strain engineering using a two-dimensional stacked carbon-MoS 2 material to control chemical storage pathways in MoS 2 upon lithium metal insertion.