Influence of gelatin on corrosion behavior of copper in acid media
This paper presents the results of gelatin and benzotriazole (BTA) inhibitory action on copper in the acid medium by the method of weight loss. The investigation was carried out in the citric acid solution (1, 5 and 20%) at the temperature of 293 K. Under such conditions, the gelatin showed higher e...
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Veröffentlicht in: | Hemijska industrija 2012, Vol.66 (2), p.193-200 |
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Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | This paper presents the results of gelatin and benzotriazole (BTA) inhibitory
action on copper in the acid medium by the method of weight loss. The
investigation was carried out in the citric acid solution (1, 5 and 20%) at
the temperature of 293 K. Under such conditions, the gelatin showed higher
efficiency of corrosion protection in comparison to BTA. The results,
obtained through the Gibbs and Langmuir adsorption isotherm, show that
gelatin adsorption on copper surface obey the Langmuir adsorption isotherm
model, as well as that the adsorption is a spontaneous process. The
polarization measurements show the potential of full passivation shift
towards more negative values, and the increase of corrosion current in both
cases but being more pronounced with the BTA. The results obtained in this
paper indicate that the inhibition gelatin can be used as the BTA substitute
for the copper corrosion protection.
nema |
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ISSN: | 0367-598X 2217-7426 |
DOI: | 10.2298/HEMIND110616089T |