Bis{2-ethoxy-6-[2-(isopropylammonio)ethyliminomethyl]phenolato}dithiocyanatonickel(II)

Bis{2-ethoxy-6-[2-(isopropylammonio)ethyliminomethyl]phenolato}dithiocyanatonickel(II)

In the mononuclear title complex, [Ni(NCS)2(C14H22N2O2)2], the Ni atom lies on an inversion centre. It is chelated by the phenolate O and imine N atoms from two zwitterionic Schiff base ligands, and is also coordinated by the N atoms from two thiocyanate ligands, giving a slightly distorted octahedr...

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Veröffentlicht in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2010-02, Vol.66 (2), p.m118-m118
Hauptverfasser: Wang, Chen-Yi, Ye, Jin-Yun, Wu, Xiang, Yuan, Cai-Jun
Format: Artikel
Sprache:eng
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Zusammenfassung:In the mononuclear title complex, [Ni(NCS)2(C14H22N2O2)2], the Ni atom lies on an inversion centre. It is chelated by the phenolate O and imine N atoms from two zwitterionic Schiff base ligands, and is also coordinated by the N atoms from two thiocyanate ligands, giving a slightly distorted octahedral geometry. Intramolecular N—H...O and N—H...N hydrogen bonds are observed.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536809055780