Photothermal catalytic transfer hydrogenolysis of protolignin

Photothermal catalysis is a promising strategy to combine the advantages of both thermal-catalysis and photocatalysis. Herein we achieve the protolignin conversion to aromatics via the photothermal catalytic transfer hydrogenolysis process intensified by the in-situ protection strategy. The Pd/TiO 2 at 140 °C with UV irradiation can catalyze the reforming of primary alcohols to aldehydes and active H* species, which further participate in the acetalation protection of the 1,3-diol group of β-O-4 linkage and mediate the hydrogenolysis of C β –OAr bonds, respectively. The conversion of birch sawdust with ethanol as the hydrogen donor provides a 40 wt% yield of phenolic monomers, compared with an 11 wt% monomer yield obtained from the conversion of extracted 1,3-diol-protected lignin under the same conditions. The synergistic effect of photocatalysis and thermal-catalysis contributes to the prior cleavage of the C β –OAr bond before other C–O bonds. The feasibility of solar-light-driven photothermal catalytic system is demonstrated. Photothermal catalysis has emerged as a promising strategy to combine the advantages of single thermal catalysis with that of photocatalysis. Herein, the authors report the protolignin direct conversion to aromatics via the photothermal catalytic transfer hydrogenolysis process intensified by the in-situ protection strategy.