Mechanistic investigation of the mass transfer stages involved during the adsorption of aqueous lead onto Scopulariopsis brevicompactum fungal biomass

•S. brevicompactum (SFB) biomass was studied for effective Pb2+ removal.•The maximum Pb2+ adsorption capacity of the SFB was high.•Characterization results confirmed the presence of metal-binding groups on SFB.•Adsorptive mass transfer study suggests the dominance of film diffusion mechanism . The S...

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Veröffentlicht in:Environmental challenges (Amsterdam, Netherlands) Netherlands), 2021-12, Vol.5, p.100373, Article 100373
Hauptverfasser: Mohamed, Latifa A., Aniagor, Chukwunonso O., Taha, Ghada M., Abou-Okeil, A., Hashem, A.
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Sprache:eng
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Zusammenfassung:•S. brevicompactum (SFB) biomass was studied for effective Pb2+ removal.•The maximum Pb2+ adsorption capacity of the SFB was high.•Characterization results confirmed the presence of metal-binding groups on SFB.•Adsorptive mass transfer study suggests the dominance of film diffusion mechanism . The Scopulariopsis brevicompactum fungal biomass (SFB) was applied as an adsorbent for the uptake of aqueous lead species via the dynamic sorption process. The adsorption capacity dependence on the solution pH, contact time, initial adsorbate concentration and adsorbent concentration was investigated via batch mode. According to the experimental findings, the adsorption capacity was favoured by an increase in all the aforementioned process variables except adsorbent concentration. The optimum adsorption capacity was recorded at pH 6.0, 120 min, and 0.2 g/L adsorbent concentration. The process isotherm was explained by the D-R model, with predominated physisorption (E = 0.069 kJ/mol), while the pseudo-second-order model explained the process kinetics. The characterization results confirmed the presence of several metal-binding functional groups on SFB. Furthermore, by applying the mass transfer factor model, the dependence of the lead ions adsorptive mass transfer on the film diffusion regime was established. Thus, the adsorptive performance of the SFB was demonstrated in the study.
ISSN:2667-0100
2667-0100
DOI:10.1016/j.envc.2021.100373