Bis(1 H -benzimidazole-2-carboxylato-κ 2 N 3 , O )bis(ethanol-κ O )manganese(II)

In the title compound, [Mn(C 8 H 5 N 2 O 2 ) 2 (C 2 H 5 OH) 2 ], the Mn II atom is six-coordinated by two N and two O atoms from two 1 H -benzimidazole-2-carboxyl­ate ( L ) ligands and by two O atoms from two ethanol mol­ecules in a distorted octa­hedral geometry. The mean planes of the two L ligand...

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Veröffentlicht in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2012-10, Vol.68 (10), p.m1288-m1288
Hauptverfasser: Nie, Jian-Hua, Lin, Yue-Hua, Xu, Chun-Tao
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Sprache:eng
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Zusammenfassung:In the title compound, [Mn(C 8 H 5 N 2 O 2 ) 2 (C 2 H 5 OH) 2 ], the Mn II atom is six-coordinated by two N and two O atoms from two 1 H -benzimidazole-2-carboxyl­ate ( L ) ligands and by two O atoms from two ethanol mol­ecules in a distorted octa­hedral geometry. The mean planes of the two L ligands are inclined to each other at 7.6 (1)°. In the crystal, N—H⋯O and O—H⋯O hydrogen bonds link the mol­ecules into layers parallel to the ab plane.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536812039475