Bis(1 H -benzimidazole-2-carboxylato-κ 2 N 3 , O )bis(ethanol-κ O )manganese(II)
In the title compound, [Mn(C 8 H 5 N 2 O 2 ) 2 (C 2 H 5 OH) 2 ], the Mn II atom is six-coordinated by two N and two O atoms from two 1 H -benzimidazole-2-carboxylate ( L ) ligands and by two O atoms from two ethanol molecules in a distorted octahedral geometry. The mean planes of the two L ligand...
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Veröffentlicht in: | Acta crystallographica. Section E, Structure reports online Structure reports online, 2012-10, Vol.68 (10), p.m1288-m1288 |
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Hauptverfasser: | , , |
Format: | Artikel |
Sprache: | eng |
Schlagworte: | |
Online-Zugang: | Volltext |
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Zusammenfassung: | In the title compound, [Mn(C
8
H
5
N
2
O
2
)
2
(C
2
H
5
OH)
2
], the Mn
II
atom is six-coordinated by two N and two O atoms from two 1
H
-benzimidazole-2-carboxylate (
L
) ligands and by two O atoms from two ethanol molecules in a distorted octahedral geometry. The mean planes of the two
L
ligands are inclined to each other at 7.6 (1)°. In the crystal, N—H⋯O and O—H⋯O hydrogen bonds link the molecules into layers parallel to the
ab
plane. |
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ISSN: | 1600-5368 1600-5368 |
DOI: | 10.1107/S1600536812039475 |