Trichloroisocyanuric Acid: An Alternate Green Route for the Transformation of Alkenes into Epoxides

Trichloroisocyanuric Acid: An Alternate Green Route for the Transformation of Alkenes into Epoxides

The preparation of epoxides is efficiently achieved in mild conditions by reaction of alkenes with trichloroisocyanuric acid in aqueous acetone followed by treatment of the resulting chlorohydrin with aqueous KOH in ether / pentane.

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Veröffentlicht in:Journal of the Brazilian Chemical Society 2002-09, Vol.13 (5), p.700-703
Hauptverfasser: Wengert, Mira, Sanseverino, Antonio M., Mattos, Marcio C. S. de
Format: Artikel
Sprache:eng
Schlagworte:
alkene
CHEMISTRY, MULTIDISCIPLINARY
chlorohydrin
epoxide
green chemistry
trichloroisocyanuric acid
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Beschreibung
Zusammenfassung:The preparation of epoxides is efficiently achieved in mild conditions by reaction of alkenes with trichloroisocyanuric acid in aqueous acetone followed by treatment of the resulting chlorohydrin with aqueous KOH in ether / pentane.
ISSN:0103-5053
1678-4790
DOI:10.1590/S0103-50532002000500028