The ansa -bridged cyclopentadienyl titanium complex [{η 5 -C 5 Me 4 CH 2 -C(NMe 2 )=N}TiCl 2 ]
The title complex, dichlorido[ N , N -dimethyl-2-(η 5 -tetramethylcyclopentadienyl)acetamidinido-κ N ′]titanium(IV), [Ti(C 13 H 20 N 2 )Cl 2 ], exhibits an unusual ansa -bridged conformation. The cyclopentadienyl ring and the mean plane of the Ti—N=C—C—C fragment form a dihedral angle of 88.08 (11)°...
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| Veröffentlicht in: | Acta crystallographica. Section E, Structure reports online Structure reports online, 2009-06, Vol.65 (6), p.m611-m611 |
|---|---|
| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | The title complex, dichlorido[
N
,
N
-dimethyl-2-(η
5
-tetramethylcyclopentadienyl)acetamidinido-κ
N
′]titanium(IV), [Ti(C
13
H
20
N
2
)Cl
2
], exhibits an unusual
ansa
-bridged conformation. The cyclopentadienyl ring and the mean plane of the Ti—N=C—C—C fragment form a dihedral angle of 88.08 (11)°. |
|---|---|
| ISSN: | 1600-5368 1600-5368 |
| DOI: | 10.1107/S1600536809015839 |