Intramolecular Charge Transfer Dynamics of a Planarized Analogue of 4-(dimethylamino)benzonitrile (DMABN) by Time-Resolved Fluorescence

Intramolecular Charge Transfer Dynamics of a Planarized Analogue of 4-(dimethylamino)benzonitrile (DMABN) by Time-Resolved Fluorescence

Intramolecular charge transfer (ICT) of confined 1-tert-butyl-6-cyano-1, 2, 3, 4-tetrahydroquinoline (NTC6) is determined with a single time constant of ~1 ps regardless of solvents, although ICT of 4-(dimethylamino)benzonitrile (DMABN) shows dispersive dynamics in solvents.

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Bibliographische Detailangaben
Veröffentlicht in:EPJ Web of conferences 2013, Vol.41, p.5023-np
Hauptverfasser: Park, Myeongkee, Young Kim, So, Im, D., Rhee, Y. H., Joo, Taiha
Format: Artikel
Sprache:eng
Schlagworte:
Analogue
Benzonitrile
Charge transfer
Dynamics
Fluorescence
Solvents
Time constant
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Zusammenfassung:Intramolecular charge transfer (ICT) of confined 1-tert-butyl-6-cyano-1, 2, 3, 4-tetrahydroquinoline (NTC6) is determined with a single time constant of ~1 ps regardless of solvents, although ICT of 4-(dimethylamino)benzonitrile (DMABN) shows dispersive dynamics in solvents.
ISSN:2100-014X
2100-014X
DOI:10.1051/epjconf/20134105023